Hope this helps who ever uses this.... Just delete my company info, and add yours. Just copy cut and paste it. I could not seem to attach a file to this post?????
1. Product Identification
Synonyms: Apple Sauce
Palmetto Roof Restorations
Jeffrey Beerer
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2. Composition/Information on Ingredients
Compound CAS#/ EINECS# Percent Concentration OSHA PEL ACGIH TLV
Sodium Hypochlorite (NaOCl) 7681-52-9/ 231-668-3 3.6% 0.5 μg/mL 1 μg/mL
Trisodium Phosphate Dodecahydrate (Na3PO4 12H2O) 10101-89-0/ 231-509-8 1.5% Not Established 10 mg/m3
Sodium Tetraborate Decahydrate (B4Na2O7 10H2O) 1303-96-4/ 215-540-4 1.5% 5 mg/m3 5 mg/m3
Water 7732-18-5/ 231-791-2 Balance Not Available Not Available
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3. Hazards Identification
Emergency Overview
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WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT. CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY.
SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 1 - Slight
Contact Rating: 3 - Severe
Protective Equip: PROPER GLOVES; EYE PROTECTION; EXPOSED SKIN COVERED
Storage Color Code: Green (General Storage)
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Potential Health Effects
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Inhalation:
May cause irritation to the respiratory tract, (nose and throat); symptoms may include coughing and sore throat.
Ingestion:
May cause nausea, vomiting, diarehea. Alkali solution will cause severe irritation to burns to mouth and esphogous.
Skin Contact:
May cause severe irritation or burns to skin.
Eye Contact:
Contact may cause severe irritation or burns and damage, especially at higher concentrations.
Chronic Exposure:
A constant irritant to the eyes and throat. Low potential for sensitization after exaggerated exposure to damaged skin.
Aggravation of Pre-existing Conditions:
Persons with impaired respiratory function, or heart disorders (or disease) may be more susceptible to the effects of the substance.
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4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Can also be given milk to dilute. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If severe irritation or burns develop seek medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician:
Consider oral administration of sodium thiosulfate solutions if sodium hypochlorite is ingested. Do not administer neutralizing substances since the resultant exothermic reaction could further damage tissue. Endotracheal intubation could be needed if glottic edema compromises the airway. For individuals with significant inhalation exposure, monitor arterial blood gases and chest x-ray.
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5. Fire Fighting Measures
Fire:
Not considered to be a fire hazard. Substance releases oxygen when heated, which may increase the severity of an existing fire. Containers may rupture from pressure build-up.
Explosion:
This solution is not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire. Use water spray to cool fire-exposed containers, to dilute liquid, and control vapor.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
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6. Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. g., kitty liter, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities.
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7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.
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8. Exposure Controls/Personal Protection
Ventilation System:
Only use product in open well ventilated areas or with proper ventilation system. A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
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9. Physical and Chemical Properties
Appearance:
Colorless to yellowish liquid.
Odor:
Chlorine-like odor.
Solubility:
100% in water.
pH:
9 - 14
Boiling Point:
40C (104F) Decomposes slightly
Melting Point:
N/A
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.
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10. Stability and Reactivity
Stability:
Slowly decomposes on contact with air. Rate increases with the concentration and temperature. Exposure to sunlight accelerates decomposition. Sodium hypochlorite becomes less toxic with age.
Hazardous Decomposition Products:
Emits toxic fumes of chlorine when heated to decomposition. Sodium oxide at high temperatures. Sodium and phosphorus oxides may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Ammonia (chloramine gas may evolve),amines, ammonium salts, aziridine, methanol, phenyl acetonitrile, cellulose, ethyleneimine, oxidizable metals, acids, soaps, and bisulfates. Can react violently with acid to liberate heat.
Conditions to Avoid:
Light, heat, flames, ignition sources, incompatibles.
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11. Toxicological Information
Sodium Hypochlorite: No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated as a tumorigen and mutagen. Irritation data: eye, rabbit, 10 mg – Moderate.
Trisodium Phosphate: Investigated as a mutagen. Trisodium Phosphate, Dodecahydrate: 7400 mg/kg oral rat LD50.
Sodium Tetraborate: LD50/LC50 oral mouse is 2gm/kg; oral rat is 2660 mg/kg.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
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Sodium Hypochlorite (as NaOCl) No No 3
(7681-52-9)
Sodium Phosphate, Tribasic No No None
(7601-54-9)
Sodium Tetraborate Decahydrate No No None
(1303-96-4)
Water (7732-18-5) No No None
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12. Ecological Information
Environmental Fate:
No information found.
Environmental Toxicity:
No information found.
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13. Disposal Considerations
Dilute with water and flush to sewer if local ordinances allow, otherwise, whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
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14. Transport Information
Not regulated.
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15. Regulatory Information
TSCA Status: Components of this solution are listed on the RSCA Inventory.
RCRA Status: No
SARA: Subject to the reporting requirements of Section 313 of SARA Title III and of 40 CFR 372
Risk Phrases: R20, R34, R48. Harmful by inhalation. Causes burns. Danger of serious damage to health by prolonged exposure.
Safety Phrases: S24, S25, S36/37/39, S53. Avoid contact with the skin. Avoid contact with eyes. Wear suitable protective clothing, gloves and eye/face protection. Avoid exposure obtain special instruction before use.
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16. Other Information
NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 1
Label Hazard Warning:
WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT. CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY.
Label Precautions:
Avoid contact with eyes, skin and clothing.
Avoid breathing mist.
Keep container closed.
Use with adequate ventilation.
Wash thoroughly after handling.
Label First Aid:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases get medical attention immediately.
Product Use:
Laboratory Reagent.
Revision Information:
New
Disclaimer:
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Pallmetto Roof Restorations provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. PALLMETTO ROOF RESTORATIONS MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, PALLMETTO ROOF RESTORATIONS WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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Fri Sep 05, 2008 6:30 pm